Meaning
Tubal-cain was the first artificer in brass and iron (Gen 4:22). Hiram was noted as a worker in brass (1Kings 7:14). Copper abounded in Palestine (Deut 8:9; Isa 60:17; 1Chr 22:3, 14). All sorts of vessels in the tabernacle and the temple were made of it (Lev 6:28; Num 16:39; 2Chr 4:16; Ezra 8:27); also weapons of war (1Sam 17:5, 6, 38; 2Sam 21:16). Iron is mentioned only four times (Gen 4:22; Lev 26:19; Num 31:22; 35:16) in the first four books of Moses, while copper (rendered "brass") is mentioned forty times. (See BRASS)
We find mention of Alexander (q.v.), a "coppersmith" of Ephesus (2Tim 4:14).